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Paralleling two identical packs will double the capacity and therefore increase flight time ( over that of a single pack in the same rig ) however volts remain the same and therefore power will remain the same too. Flight time will not simply double however, as weight will have increased etc.

Series will double the voltage and therefore current drawn and power produced will also increase, and duration reduce. 

Of course simply connecting 2 of them in series, on a rig that was setup to use the one only, will almost certainly let out the magic smoke. 

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Philip

As far as the lipos are concerned series or parallel doesn't make any difference to the power available. In series the voltage is doubled, in parallel the current is doubled but the total power output is the same. So it really comes down to your ESC, motor and prop combination as to which configuration best keeps within the 20c (40 amp) battery limit.

If you do have a suitable ESC, motor & prop, a series configuration (higher voltage, lower current) is slightly more efficient as the electrical losses are lower but remember it is your airframe that is absorbing all the power so even a slight improvement in that will result in an improvement in overall performance. 

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No If you put them in series it will sill only be 20C but twice the voltage.

So

2x11.1  in series  = 22.2v at 2200ma capacity.  20c is 44A  .In series you have done nothing to increase the capacity only the voltage but the amount of power available is twice that of a single pack.

volts x amps = watts so  22.2 x 44 = 976  watts . High voltage low current

2x 11.1 in parallel = 11.1v at 4400ma capacity.  20c is 88A .

volts x amps = watts so  11.1 x 88 =  976 watts Low voltage  High current

If the set up you were using was an 11.1 v set up and you were using a 2200 ma pack and you added an identical pack in parallel to it you would get nearly 2 x the flight time ( remembering it is heaver)

If the set up you were using was an 11.1 v set up and you were using a 2200 ma pack and you added an identical pack in series you would  smoke the system unless you changed the motor or prop or both as you are trying to get the prop to spin faster as the voltage has increased . Remember one of the specs of a motor is RPM per volt.

Its Late on Xmas Day

Good night.

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